3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) 451-2500, Ext. 2222 Transportation Emergency Telephone (CANUTEC): (613) 996-6666 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 06-3743-9 Issue date : 07/16/2004 Version : 15.00 Supersedes date : 07/25/2001 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Environmental Health and Safety Services Department, 3M Canada Company Telephone: (519) 452-2161, Fax: (519) 452-6015, Web Site: www.3M.ca ----------------------------------------------------------------------- 1 Product Identification ----------------------------------------------------------------------- Tradename: 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) (INACTIVE) Product ID: 42-0011-1354-9 98-0400-2668-8 Intended Use of Product: Fire Protection Division: SPECIFIED CONSTRUCTION PRODUCTS ----------------------------------------------------------------------- 2 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- SYNTHETIC POLYMER LATEX None 20.0 - 30.0 ZINC BORATE HYDRATE 12447-61-9 20.0 - 25.0 WATER 7732-18-5 20.0 - 30.0 SODIUM SILICATE 1344-09-8 10.0 - 16.0 2-ETHYLHEXYLDIPHENYL PHOSPHATE 1241-94-7 5.0 - 6.0 ZINC BORATE 1332-07-6 2.5 - 3.5 IRON OXIDE 1309-37-1 2.0 - 3.0 FLAME RETARDANT None 1.5 - 3.0 TRADE SECRET None < 2.0741 CHOPPED FIBERGLASS 65997-17-3 1.0 - 2.0 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 2 of 8   (INACTIVE) ----------------------------------------------------------------------- VINYL ACETATE 108-05-4 < 0.2 FORMALDEHYDE 50-00-0 < 0.03 NOTE: SYNTHETIC POLYMER LATEX has no CAS number. FLAME RETARDANT; has no CAS number. TRADE SECRET has no CAS number. ----------------------------------------------------------------------- 3 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: No data available. See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention. Instructions for Inhalation: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. Instructions for Ingestion: Do not induce vomiting. Drink two glasses of water. Call a physician. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: Not applicable Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable Autoignition temperature: Not applicable Suitable Extinguishing Media: Non-flammable Exposure Hazards during Fire: No unusual fire or explosion hazards are anticipated. Combustion Products from Fire: None known. Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 3 of 8   (INACTIVE) ----------------------------------------------------------------------- protective covering for exposed areas of the head. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Spill Response: Clean up residue. Methods for Disposal: Dispose of waste product in a sanitary landfill. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Store at temperatures above 32 degrees F (O degrees C). Incompatible Materials: Store away from heat. Ventilation: No data available. Fire Prevention: Not applicable. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact. Skin Protection: Avoid prolonged or repeated skin contact. Respiratory Protection: Avoid prolonged breathing of vapours. Ingestion (Prevention): Wash hands after handling and before eating. Recommended Ventilation: No hazards anticipated. However, provide ventilation adequate to control odors. Ingredient Exposure Data ------------------------ 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 4 of 8   (INACTIVE) ----------------------------------------------------------------------- SYNTHETIC POLYMER LATEX (None) Specific Ingredient Data: No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. ZINC BORATE HYDRATE (12447-61-9) Specific Ingredient Data: No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. WATER (7732-18-5) LD50 (rat, oral): >90 ml/kg LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. SODIUM SILICATE (1344-09-8) Specific Ingredient Data: No data available. LD50 (rat, oral): 3.3 -8.4 g/kg LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. 2-ETHYLHEXYLDIPHENYL PHOSPHATE (1241-94-7) Specific Ingredient Data: No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. ZINC BORATE (1332-07-6) Specific Ingredient Data: No data available. No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. IRON OXIDE (1309-37-1) LD50 (rat, oral): >10,000 mg/kg 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 5 of 8   (INACTIVE) ----------------------------------------------------------------------- LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits: ACGIH: TWA 5 mg/m3 (specific form) as Fe; (Table A4) FLAME RETARDANT (None) Specific Ingredient Data: No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. TRADE SECRET (None) LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits : No data available. CHOPPED FIBERGLASS (65997-17-3) Specific Ingredient Data: No data available. LD50 (rat, oral) : No data available. LC50 (rat, inhalation/4 hours) : No data available. Exposure Limits: 3M: TWA 10 mg/m3 as dust VINYL ACETATE (108-05-4) LD50 (rat, oral): 2920 mg/kg LC50 (rat, inhalation/4 hours): 3250 -4100 ppm Exposure Limits: ACGIH: TWA 10 ppm (Table A3) ACGIH: TWA 35 mg/m3 (Table A3) ACGIH: STEL 15 ppm (Table A3) ACGIH: STEL 53 mg/m3 (Table A3) CMRG: TWA  5 ppm FORMALDEHYDE (50-00-0) LD50 (rat, oral): 100 mg/kg LD50 (dermal, rabbit):  270 uL/kg LC50 (rat, inhalation/4 hours): 203 mg/m3 Exposure Limits: ACGIH: CEIL 0.3 ppm Sensitizer; (Table A2) 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 6 of 8   (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Thixotropic; paste; Caulk; brown; negligible odour; Odour Threshold: No data available. pH: 7.5 -8.0 Boiling point/boiling range: Approximately100 C Melting point/melting range: Not available Vapour pressure: Approximately17.5 mmHg Water Solubility: Complete Specific gravity: Approximately1.35 g/ml Vapour density: Not available Volatile organic compounds: Not available Evaporation rate: Approximately.33 BuOAc=1 Viscosity: Approximately12000 poise Brookfield Percent Volatile: No data available. ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition: None known Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact: Mild Skin Irritation: Signs/symptoms can include localized redness, swelling, and itching. Effects from Inhalation: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Ingestion is not a likely route of exposure to this product. Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 7 of 8   (INACTIVE) ----------------------------------------------------------------------- may include abdominal pain, nausea, diarrhea and vomiting. Sensitization Information: No data available. Carcinogenicity: No data available. Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Ecotoxicity Data: No data available. Ecofate Data: Other Effects and Information: No data available. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: No data available. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transportation Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material International Dangerous Goods Classification -------------------------------------------- 3M BRAND FIRE BARRIER CP-25 WB+ CAULK (REVISED) Page 8 of 8   (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: Not Controlled NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: EINECS - European Inventory of Existing Commercial Chemical Substances AICS - Australian Inventory of Chemical Substances DSL - Domestic Substances List (Canada) KTCCL - Korean Toxic Chemical Control Law ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Update Tradename (Obsolete product) The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---